Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine Câ N bond
Gandelman, Mark; Milstein, David; Gandelman Mark; Department of Organic Chemistry, The Weizmann Institute of Science; Milstein David; Department of Organic Chemistry, The Weizmann Institute of Science
Журнал:
Chemical Communications
Дата:
2000
Аннотация:
Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butylphosphinomethyl)-2,4,6-tri methylbenzene (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained Câ N single bond.
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