A novel alkoxide bridging motif between boron trifluoride and copper(ii) in a crown thioether complex
Sutton, Liam R.; Blake, Alexander J.; Cooke, Paul A.; Schröder, Martin; Sutton Liam R.; School of Chemistry, The University of Nottingham; Blake Alexander J.; School of Chemistry, The University of Nottingham; Cooke Paul A.; School of Chemistry, The University of Nottingham; Schröder Martin; School of Chemistry, The University of Nottingham
Журнал:
Chemical Communications
Дата:
2000
Аннотация:
Reaction of 6-hydroxy-1,4,8,11-tetrathiacyclotetradecane (LH) with Cu(BF4)2 in THF yields [Cu(LH)](BF4)2; crystallisation of the complex from MeNO2/Et2O gives brown crystals of [Cu(LBF3)](BF4), the first example of alkoxide bridging between BF3 and a metal centre.
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