Solâ gel entrapped TEMPO for the selective oxidation of methyl α-d-glucopyranosideElectronic Supplementary Information (ESI) available: details of the preparation of a typical catalyst and its use in the oxidation of MGP to the corresponding uronate. See http://www.rsc.org/suppdata/cc/b0/b003096l/
Ciriminna, Rosaria; Blum, Jochanan; Avnir, David; Pagliaro, Mario; Ciriminna Rosaria; Institute of Chemistry and Technology of Natural Products, CNR; Blum Jochanan; Institute of Chemistry, The Hebrew University of Jerusalem; Avnir David; Institute of Chemistry, The Hebrew University of Jerusalem; Pagliaro Mario; Institute of Chemistry and Technology of Natural Products, CNR
Журнал:
Chemical Communications
Дата:
2000
Аннотация:
The solâ gel entrapment of TEMPO within a silica matrix yields an efficient and recyclable catalytic system for the selective oxidation of methyl α-d-glucopyranoside (MGP) in water with NaOCl as primary oxidant, thus opening the way to the heterogeneous catalysis of the conversion of sugars into valuable uronates.
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