Syntheses and structural characterization of novel luminescent heteronuclear rhenium(i)â zinc(ii) and â cadmium(ii) chalcogenolate complexesElectronic supplementary information (ESI) available: characterization for complexes 1â 6 and experimental crystallographic details for 2. See http://www.rsc.org/suppdata/cc/b0/b005092j/
Yam, Vivian Wing-Wah; Pui, Yung-Lin; Wong, Keith Man-Chung; Cheung, Kung-Kai; Yam Vivian Wing-Wah; Department of Chemistry, The University of Hong Kong; Pui Yung-Lin; Department of Chemistry, The University of Hong Kong; Wong Keith Man-Chung; Department of Chemistry, The University of Hong Kong; Cheung Kung-Kai; Department of Chemistry, The University of Hong Kong
Журнал:
Chemical Communications
Дата:
2000
Аннотация:
Novel heteronuclear rhenium(i)â zinc(ii) and â cadmium(ii) complexes with chalcogenolate ligands have been synthesized and shown to exhibit rich luminescence properties; the X-ray crystal structures of [{(bpy)Re(CO)3(μ-SC6H4Me-p )}2- Zn(bpy)](PF6)2 (2) and [{(bpy)Re(CO)3(μ-SC6H4Me-p )}2- Cd(bpy)2](PF6)2 (4) have been determined.
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