[Pt2(GaCp*)2(μ2-Ga Cp*)3]: structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands
Weià , Dana; Winter, Manuela; Fischer, Roland A.; Yu, Chen; Wichmann, Karin; Frenking, Gernot; Weià Dana; Lehrstuhl für Anorganische Chemie II, Organometallics & Materials Chemistry, Ruhr-Universität Bochum; Winter Manuela; Lehrstuhl für Anorganische Chemie II, Organometallics & Materials Chemistry, Ruhr-Universität Bochum; Fischer Roland A.; Lehrstuhl für Anorganische Chemie II, Organometallics & Materials Chemistry, Ruhr-Universität Bochum; Yu Chen; Fachbereich Chemie, Philipps-Universität Marburg; Wichmann Karin; Fachbereich Chemie, Philipps-Universität Marburg; Frenking Gernot; Fachbereich Chemie, Philipps-Universität Marburg
Журнал:
Chemical Communications
Дата:
2000
Аннотация:
A new homoleptic diplatinum complex [Pt2(GaCp*)2(μ2-GaCp*)3] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum atoms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)6 and was characterized by structural and quantum chemical methods.
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