| Автор | Gemel, Christian |
| Автор | John, Roland |
| Автор | Slugovc, Christian |
| Автор | Mereiter, Kurt |
| Автор | Schmid, Roland |
| Автор | Kirchner, Karl |
| Дата выпуска | 2000 |
| dc.description | The complex [Ru(η<sup>6</sup>-p-MeC6H4Pr<sup>i</sup>)Cl2]2 reacted with K[quin] (quinâ =â quinolin-8-olate) to yield the half-sandwich complex Ru(η<sup>6</sup>-p-MeC6H4Pr<sup>i</sup>)(quin)Cl 1. Chloride abstraction from 1 with AgCF3SO3 affords the neutral complex Ru(η<sup>6</sup>-p-MeC6H4Pr<sup>i</sup>)(quin)(κ<sup>1</sup>O-CF3SO3). The lability of the CF3SO3<sup>â </sup> ligand in 2 is apparent by the reaction with CH3CN giving [Ru(η<sup>6</sup>-p-MeC6H4Pr<sup>i</sup>)(quin)(CH3CN)]CF3SO3 3. Refluxing RuTp(COD)Cl in the presence of K[quin] resulted in the formation of Ru(COD)(quin)2 4 containing no Tp ligand; 4 has also been obtained in good yield by treating [Ru(COD)Cl2]n with K[quin] in boiling methanol. Treatment of either 1 or 3 with 1 equivalent of KTp resulted in the formation of the unusual complex Ru(η<sup>6</sup>-p-MeC6H4Pr<sup>i</sup>)(quin)(κ<sup>1</sup>N-Tp) (5) featuring a κ<sup>1</sup>-co-ordinated Tp ligand. However, if 1 is treated with KTp in the presence of AgCF3SO3 the cationic complex [Ru(η<sup>6</sup>-p-MeC6H4Pr<sup>i</sup>)(quin)(κ<sup>1</sup>-Hpz)]CF3SO3 6 is obtained containing a pyrazole ligand as a result of Bâ N bond cleavage. Complexes 1, 4, 5, and 6 have been characterized by X-ray crystallography. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Synthesis and characterization of ruthenium quinolin-8-olate complexes. Unexpected formation of a κ<sup>1</sup>-hydrotris(pyrazolyl)borate complex |
| Тип | ART |
| Журнал | Dalton Transactions |
| Первая страница | 2607 |
| Последняя страница | 2612 |
| Аффилиация | Gemel Christian; Institute of Inorganic Chemistry, Vienna University of Technology |
| Аффилиация | John Roland; Institute of Inorganic Chemistry, Vienna University of Technology |
| Аффилиация | Slugovc Christian; Institute of Inorganic Chemistry, Vienna University of Technology |
| Аффилиация | Mereiter Kurt; Institute of Mineralogy, Crystallography, and Structural Chemistry, Vienna University of Technology |
| Аффилиация | Schmid Roland; Institute of Inorganic Chemistry, Vienna University of Technology |
| Аффилиация | Kirchner Karl; Institute of Inorganic Chemistry, Vienna University of Technology |
| Выпуск | 15 |
| Библиографическая ссылка | M. O. Albers, D. J. Robinson, A. Shaver, E. Singleton, Organometallics, 1986, 5, 2199 |
| Библиографическая ссылка | E. Rüba, W. Simanko, K. Mereiter, R. Schmid, K. Kirchner, Inorg. Chem., 2000, 39, 382 |
| Библиографическая ссылка | W. Luginbühl, P. Zbinden, P. A. Pittet, T. Armbruster, H. B. Bürgi, A. E. Merbach, A. Ludi, Inorg. Chem., 1991, 30, 2350 |
| Библиографическая ссылка | T. P. Gill, K. R. Mann, Organometallics, 1982, 1, 485 |
| Библиографическая ссылка | S. Trofimenko, Inorg. Synth., 1970, 12, 99 |
| Библиографическая ссылка | M. A. Bennett, A. K. Smith, J. Chem. Soc., Dalton Trans., 1974, 233 |
| Библиографическая ссылка | I. del Rio, R. A. Gossage, M. S. Hannu, M. Lutz, A. L. Spek, G. van Koten, A. C. Ontko, J. F. Houlis, R. C. Schnabel, D. M. Roddick, T. P. Fong, A. J. Lough, R. H. Morris, C. Gemel, D. Kalt, K. Mereiter, V. N. Sapunov, R. Schmid, K. Kirchner, K. Mauthner, C. Slugovc, K. Mereiter, R. Schmid, K. Kirchner, J. P. Sutter, S. L. James, P. Steenwinkel, T. Karlen, D. M. Grove, N. Veldman, W. J. J. Smeets, A. L. Spek, G. van Koten, M. J. A. Kraakman, B. de Klerk-Engels, P. P. M. de Lange, K. Vrieze, W. J. J. Smeets, A. L. Spek, P. W. Plosse, J. C. Gallucci, A. Wojcicki, See, Organometallics, 1999, 18, 1097, Organometallics, 1999, 17, 5467, Organometallics, 1997, 16, 427, Organometallics, 1997, 16, 1956, Organometallics, 1996, 15, 941, Organometallics, 1992, 11, 3774, Inorg. Chem., 1992, 31, 2376 |
| Библиографическая ссылка | C. Slugovc, K. Kirchner, Coord. Chem. Rev., 1999, 185â 186, 109 |
| Библиографическая ссылка | M. Menon, A. Pramanik, N. Bag, A. Chakravorty, J. Chem. Soc., Dalton Trans., 1995, 1417 |
| Библиографическая ссылка | S. Bhambri, D. A. Tocher, J. Chem. Soc., Dalton Trans., 1997, 3367 |
| Библиографическая ссылка | M. Paneque, S. Sirol, M. Trujillo, E. Gutierrez-Puebla, M. A. Monge, E. Carmona, Angew. Chem., Int. Ed., 2000, 39, 218 |
| Библиографическая ссылка | T. O. Northcutt, R. J. Lachicotte, W. D. Jones, Organometallics, 1998, 17, 5148 |
| Библиографическая ссылка | M. Akita, K. Ohta, Y. Takahashi, S. Hikichi, Y. Moro-Oka, Organometallics, 1997, 16, 4121 |
| Библиографическая ссылка | E. Gutierrez, S. A. Hudson, A. Monge, M. C. Nicasio, M. Paneque, E. Carmona, E. Gutierrerz, S. A. Hudson, A. Monge, M. C. Nicasio, M. Peneque, E. Carmona, H. F. Malbosc, P. Kalck, J.-C. Daran, M. Etienne, H. V. R. Dias, W. Jin, J. Organomet. Chem., 1998, 551, 215, J. Chem. Soc., Dalton Trans., 1992, 2651, J. Chem. Soc., Dalton Trans., 1999, 271, Inorg. Chem., 1996, 35, 3687 |
| Библиографическая ссылка | E. Rüba, K. Mauthner, W. Simanko, K. M. Soldouzi, C. Slugovc, K. Mereiter, R. Schmid, K. Kirchner, Organometallics, 1999, 18, 3843 |
| Библиографическая ссылка | F. A. Jalon, A. Otero, A. Rodriguez, M. M. Khan, P. S. Roy, K. Venkatasubramaniam, N. H. Khan, P. L. Jones, K. L. V. Mann, J. C. Jeffery, J. A. McCleverty, M. D. Ward, J. Chem. Soc., Dalton Trans., 1995, 1629, Inorg. Chim. Acta, 1990, 176, 49, Polyhedron, 1997, 16, 2435 |
