An unusual observation in the rhodium carbenoids: [1,4]-migration in the sugar-derived α-diazo-β-ketoesters
Desai, Vijaya N.; Saha, Nabendu N.; Dhavale, Dilip D.; Desai Vijaya N.; Department of Chemistry, Garware Research Centre, University of Pune; Saha Nabendu N.; Department of Chemistry, Garware Research Centre, University of Pune; Dhavale Dilip D.; Department of Chemistry, Garware Research Centre, University of Pune
Журнал:
Journal of the Chemical Society, Perkin Transactions 1
Дата:
2000
Аннотация:
In competition with [1,2]-migration, [2,3]-sigmatropic rearrangement and Câ H insertion, product formation via an unusual [1,4]-migration is also found to be a prominent process in the rhodium carbenoids derived from sugar α-diazo-β-keto esters 2aâ d.
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