A simple synthesis of protoadamantene and 2,4-dehydroadamantane
Boyd, J.; Overton, K. H.
Журнал:
Journal of the Chemical Society D: Chemical Communications
Дата:
1971
Аннотация:
2-Adamantyl methanesulphonate has been converted by pyrolysis in 95% yield into a mixture (2 : 3) of protoadamantene (4) and 2,4-dehydroadamantane (5); hydroboration of protoadamantene and oxidation afforded protoadamantan-4- and -5-ones (5 : 4).
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