Reactions of liquid sodium with transition-metal oxides. Part V. The oxides Fe3O4, Co3O4, and NiO; stoicheometry and reaction rates
Addison, C. C.; Pulham, R. J.
Журнал:
Journal of the Chemical Society, Dalton Transactions
Дата:
1972
Аннотация:
The stoicheiometry and rates of reaction of liquid sodium with the oxides Fe3O4, Co3O4, and NiO have been studied by measuring the quantity of sodium consumed over a range of reaction times and temperatures. The nickel oxide reaction becomes rapid above 150°, and the sodium consumed corresponds precisely to complete reduction to nickel metal. Reaction of Fe3O4 is slow below 250°; reduction to metallic iron is only 80% complete at 250°, and this is attributed to ternary oxide formation. The oxide Co3O4 reacts rapidly below 120°, and explosively above this temperature. Reduction to cobalt metal is about 90% complete at 120°.
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