Автор |
Bott, Simon G. |
Автор |
Clark, David L. |
Автор |
Green, Malcolm L. H. |
Автор |
Mountford, Philip |
Дата выпуска |
1989 |
dc.description |
Treatment of {[W2Cl7(THF)5]Na} with excess of alkyne gives the dimetallatetrahedrane compounds, [W2Cl4(µ-Cl)2(µ-C2RR⠲)(THF)2](R = R⠲= H, Me, Et; R = H, R⠲= Ph); the X-ray crystal structure of [W2Cl4(µ-Cl)2(µ-C2Me2)(THF)2](1) reveals a confacial bioctahedral co-ordination environment about the ditungsten centre with a bridging alkyne unit. |
Формат |
application.pdf |
Издатель |
Royal Society of Chemistry |
Название |
Synthesis and X-ray crystal structure of the tungsten dimetallatetrahedrane complex[W2Cl4(µ-Cl)2(µ-C2Me2)(THF)2](THF = tetrahydrofuran) |
Тип |
research-article |
DOI |
10.1039/C39890000418 |
Print ISSN |
0022-4936 |
Журнал |
Journal of the Chemical Society, Chemical Communications |
Первая страница |
418 |
Последняя страница |
419 |
Выпуск |
7 |