Reversible dihydrogen addition to a tungsten–tungsten triple bond: X-ray crystal structure of {[W(η-C5H4Pri)Cl2]2}
Green, Malcolm L. H.; Mountford, Philip
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1989
Аннотация:
Reduction of [W(η-C5H4R)Cl4] with sodium amalgam gives {[W(η-C5H4R)Cl2]2}[(1)a; R = Me, b; R = Pr<sup>i</sup>], in which the unsupported tungstenâ tungsten triple bond [Wâ W 2.3678(6)à ] undergoes facile reversible addition of dihydrogen.
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