Metallation of a crown thioether ligand. Synthesis, structure and reactivity of [Pt(L1)][BF4] and structure of [PtI2(L1)][BF4](L1= 2,6,10-trithia[11]-m-benezenophane)
Hanan, Garry S.; Kickham, James E.; Loeb, Stephen J.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1991
Аннотация:
Metallation of L<sup>1</sup> results in formation of the square-planar, crown thioether complex [Pt(L<sup>1</sup>)][BF4]1; the versatility of this S3C donor ligand is demonstrated by substitution for the central S donor and oxidative-addition to octahedral complexs of Pt<sup> IV </sup>.
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