Автор |
Lowthian, Philip J. |
Автор |
Thompson, Michael |
Дата выпуска |
2002 |
dc.description |
Kernel density estimation is a method for producing a smooth density approximation to a dataset and avoiding some of the problems associated with histograms. If it is used with a degree of smoothing determined by a fitness for purpose criterion, it can be applied to proficiency test data in order to test for multimodality in the z-scores. The bootstrap is an essential additional technique to determine how rugged the initially estimated kernel density is: the random resampling of the data in the bootstrap simulates a complete blind repeat of the proficiency test. In addition, useful estimates of the standard error of a mode can be thus obtained. It is suggested that a mode and its standard error can be used as an assigned value and its standard uncertainty. |
Формат |
application.pdf |
Издатель |
Royal Society of Chemistry |
Название |
Bump-hunting for the proficiency tester—searching for multimodality |
Тип |
research-article |
DOI |
10.1039/b205600n |
Electronic ISSN |
1364-5528 |
Print ISSN |
0003-2654 |
Журнал |
Analyst |
Том |
127 |
Первая страница |
1359 |
Последняя страница |
1364 |
Аффилиация |
Lowthian Philip J.; School of Biological and Chemical Sciences, Birkbeck College (University of London) |
Аффилиация |
Thompson Michael; School of Biological and Chemical Sciences, Birkbeck College (University of London) |
Выпуск |
10 |
Библиографическая ссылка |
Thompson, Pure Appl. Chem., 1993, 65, 2123 |
Библиографическая ссылка |
R. E. Lawn , M.Thompson and R. F.Walker, Proficiency Testing in Analytical Chemistry, The Royal Society of Chemistry, Cambridge, UK, 1997 |
Библиографическая ссылка |
J. A. Rice , Mathematical Statistics and Data Analysis, Duxbury Press, Belmont CA, 2nd edn., 1996, pp. 321–328 |
Библиографическая ссылка |
B. W. Silverman , Density Estimation for Statistics and Data Analysis, Chapman and Hall, London, 1986 |
Библиографическая ссылка |
Cofino, Chemom. Intell. Lab. Syst., 2000, 53, 37 |
Библиографическая ссылка |
B. Efron and R. J.Tibshirani, An Introduction to the Bootstrap, Chapman and Hall, 1993, London, 1986 |
Библиографическая ссылка |
Methods Committee, Analyst, 1989, 114, 1693 |