Low temperature stopped-flow studies in inorganic chemistryBased on the presentation given at Dalton Discussion No. 4, 10–13th January 2002, Kloster Banz, Germany.
Weitzer, Markus; Schatz, Markus; Hampel, Frank; Heinemann, Frank W.; Schindler, Siegfried; Weitzer Markus; Institute of Inorganic Chemistry, University of Erlangen-Nürnberg; Schatz Markus; Institute of Inorganic Chemistry, University of Erlangen-Nürnberg; Hampel Frank; Institute of Organic Chemistry, University of Erlangen-Nürnberg; Heinemann Frank W.; Institute of Inorganic Chemistry, University of Erlangen-Nürnberg; Schindler Siegfried; Institute of Inorganic Chemistry, University of Erlangen-Nürnberg
Журнал:
Journal of the Chemical Society, Dalton Transactions
Дата:
2002
Аннотация:
Low temperature stopped-flow methods together with diode array instrumentation have become extremely useful for studying reactions that are too fast at ambient temperatures and/or for detecting reactive intermediates that can only be observed at low temperatures. Furthermore, global analysis fitting methods are described that allow the analysis of complex reaction mechanisms. To illustrate the method the reaction of dioxygen with the tripodal copper(i) complex [Cu(Me2-uns-penp)(CH3CN)]ClO4 (Me2-uns-penp = (2-dimethylaminoethyl)bis(2-pyridylmethyl)amine) is discussed as an example.
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