| Автор | Long, Nicholas J. |
| Автор | Parker, David G. |
| Автор | Speyer, Paul R. |
| Автор | White, Andrew J. P. |
| Автор | Williams, David J. |
| Дата выпуска | 2002 |
| dc.description | The synthesis of a range of methylated and non-methylated triazacyclododecane derivatives featuring the unsymmetrical incorporation of a 4-vinylbenzene side-arm is reported, along with the X-ray crystal structure of an amidinium salt precursor, and NMR characterisation of these ligands. The free amine, 1-(4-vinylbenzyl)-1,5,9-triazacyclododecane (5), has been reacted with a series of transition metal centres and the coordination chemistry is discussed, with structural analysis of an unusual triply-bridged (via one aqua and two chloride ligands) Ni(ii) dimer and a mononuclear W(CO)5 complex. Co-polymerisation studies on 5 and its metal complexes with varying percentages of styrene show the formation of low and high (via cross-linking) molecular weight polymers. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Synthesis, characterisation and polymerisation of vinylbenzene-substituted triazacyclododecanes and their transition metal complexes |
| Тип | research-article |
| DOI | 10.1039/b108235n |
| Electronic ISSN | 1364-5447 |
| Print ISSN | 1472-7773 |
| Журнал | Journal of the Chemical Society, Dalton Transactions |
| Первая страница | 2142 |
| Последняя страница | 2150 |
| Аффилиация | Long Nicholas J.; Department of Chemistry, Imperial College of Science, Technology and Medicine |
| Аффилиация | Parker David G.; ICI Technology, Research and Technology Centre |
| Аффилиация | Speyer Paul R.; Department of Chemistry, Imperial College of Science, Technology and Medicine |
| Аффилиация | White Andrew J. P.; Department of Chemistry, Imperial College of Science, Technology and Medicine |
| Аффилиация | Williams David J.; Department of Chemistry, Imperial College of Science, Technology and Medicine |
| Выпуск | 10 |
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