| Автор | Schubert, Ulrich |
| Автор | Hörnig, Hannelore |
| Автор | Erdmann, Kai-Uwe |
| Автор | Weiss, Karin |
| Дата выпуска | 1984 |
| dc.description | The carbene complexes (CO)5WC(OEt)SiPh3(1) and (CO)5WC(NEt2)SiPh3(2) thermally decompose to give triphenylsilane, ethylene, and W(CO6) or (CO)5WCNEt, respectively, while in the presence of moist CO, [Ph3Si(EtO)CHC(O)]2O is formed, believed to arise via the ketene intermediate, Ph3Si(EtO)C.dbd6;C.dbd6;O. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | A thermally induced novel fragmentation reaction of transition metal silylcarbene complexes |
| Тип | research-article |
| DOI | 10.1039/C39840000013 |
| Print ISSN | 0022-4936 |
| Журнал | Journal of the Chemical Society, Chemical Communications |
| Первая страница | 13 |
| Последняя страница | 14 |
| Выпуск | 1 |
