| Автор | Bushnell, Gordon W. |
| Автор | Stobart, Stephen R. |
| Автор | Vefghi, Rahmatollah |
| Автор | Zaworotko, Michael J. |
| Дата выпуска | 1984 |
| dc.description | Reaction of [Ir(cod)(µ-pz)]2(cod = cyclo-octa-1,5-diene; pzH = pyrazole)with Ph2PH results in hydrogenation of cod at one Ir centre to give a 1-Ï ,4-5-η-C8H13(i.e. -enyl) unit, affording the complex [Ir(cod)(µ-pz)(µ-PPh2)2Ir(C8H13)] in which Irâ Ir = 2.780 à and both pz and PPh2ligands occupy unsymmetrical bridging positions. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Addition of diphenylphosphine to a bis(µ-pyrazolyl)di-iridium(I)complex resulting in h-transfer to co-ordinated cyclo-octa-1,5-diene: X-ray crystal structure of an iridium dimer incorporating unsymmetrical pyrazolyl and phosphido bridging groups and a 1-σ,4-5-η-C8H13ligand |
| Тип | research-article |
| DOI | 10.1039/C39840000282 |
| Print ISSN | 0022-4936 |
| Журнал | Journal of the Chemical Society, Chemical Communications |
| Первая страница | 282 |
| Последняя страница | 284 |
| Выпуск | 5 |
