| Автор | Baird, Gordon J. |
| Автор | Davies, Stephen G. |
| Автор | Jones, Richard H. |
| Автор | Prout, Keith |
| Автор | Warner, Peter |
| Дата выпуска | 1984 |
| dc.description | [(η-<sup>2</sup>C5H5)Fe(PPh3)(CO)(Mthoxycarbene)]<sup>+</sup> complexes, prepared either from terminal acetylenes or from the corresponding acyl complexes, are stereoselectively deprotonated, as evidenced by the crystal structure of (Z)-[(η<sup>5</sup>-C5H5)Fe(PPh3)(CO)(COMe.dbd;CHMe)], to (Z)-methoxyvinyl complexes which can be stereoselectively alkylated under mild conditions to give elaborated acyl complexes. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Stereoselective carbon–carbon bond formation via alkylation of [(η-5C5H5)Fe(PPh3)(CO)(COMeCHR)](R = Me,Prn,Ph): X-ray crystal structure of (Z)-[(η5-C5H5)Fe(PPh3)(CO)(COMeCHMe)] |
| Тип | research-article |
| DOI | 10.1039/C39840000745 |
| Print ISSN | 0022-4936 |
| Журнал | Journal of the Chemical Society, Chemical Communications |
| Первая страница | 745 |
| Последняя страница | 747 |
| Выпуск | 12 |
