| Автор | Demerseman, Bernard |
| Автор | Mahé, Roger |
| Автор | Dixneuf, Pierre H. |
| Дата выпуска | 1984 |
| dc.description | The titanium derivatives CpCp⠲TiX2(Cp η<sup>5</sup>-C5H5; Cp⠲=η<sup>5</sup>-C5Me5; X = Me, Ph, or CO) have been synthesized and the reaction of CpCp⠲Ti(CO)2 with diphenylacetylene and trimethylphosphine affords the unsaturated (alkyne)titanium(II) complex CpCp⠲Ti(C2Ph2) which readily adds carbon dioxide to give the metallacyclic compound [graphic omitted] via carbon-carbon bond formation. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | A novel unsaturated (alkyne)titanium(II) complex (η5-C5H5)(η5-C5Me5)Ti(Ph–CC–Ph) and its coupling reaction with carbon dioxide |
| Тип | research-article |
| DOI | 10.1039/C39840001394 |
| Print ISSN | 0022-4936 |
| Журнал | Journal of the Chemical Society, Chemical Communications |
| Первая страница | 1394 |
| Последняя страница | 1396 |
| Выпуск | 21 |
