| Автор | Hamilton, James G. |
| Автор | Rooney, John J. |
| Дата выпуска | 1984 |
| dc.description | It is argued that direct [2 + 2] cycloadditions and cycloreversions involving Mt.dbd;C and C.dbd;C species and quasi-metallacyclobutanes are the key steps in olefin metathesis. This theoretical concept is then extended in a novel fashion to describe the mechanisms of many other important reactions in homogeneous and heterogeneous catalysis, and especially the activation of C.dbd;C, Hâ H and Câ H bonds by metalâ alkyl complexes where the metal ion is electron deficient and the alkyl ligand assumes â carbenoidâ character. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | The role of [2 + 2] cycloaddition-type reactions in catalysis. Activation of H—H, C—H and CC bonds by metal complexes |
| Тип | research-article |
| DOI | 10.1039/F19848000129 |
| Print ISSN | 0300-9599 |
| Журнал | Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases |
| Том | 80 |
| Первая страница | 129 |
| Последняя страница | 134 |
| Выпуск | 1 |
