Electrophilic addition of oxygen, sulphur, and selenium to η2-CS2and η2-CS2Me cobalt complexes
Bianchini, C.; Meli, A.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1983
Аннотация:
The reactions of oxygen, sulphur, and selenium with the complexes [(triphos)Co(η <sup>2</sup>CS2)] and [(triphos)Co(η <sup>2</sup>CS2Me)] BPH4[triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane] are described; these reactions provide evidence for the carbenoid nature of the metalâ (η <sup>2</sup>-CS2)and metalâ (η <sup>2</sup>-CS2Me) moieties.
192.8Кб