| Автор | Holmer, Bruce K. |
| Автор | Child, Mark S. |
| Дата выпуска | 1983 |
| dc.description | A quantum-mechanical theory for state-selected unimolecular decomposition is developed in terms of the cumulative effect of a succession of internal collisions. An application to the model decomposition of CO2 to CO(<sup>1</sup>Σ<sup>+</sup>)+ O(<sup>1</sup>D) is developed within the restrictions of a forced harmonic oscillator approximation for the internal scattering matrix. Preliminary results over a restricted energy range yield a distribution of lifetimes over two orders of magnitude, 0.6â 60 ps, with evidence of a statistically determined behaviour on average but with wide fluctuations and with significant quantum effects on the branching ratios to different product channels. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | A quantum-mechanical internal-collision model for state-selected unimolecular decomposition |
| Тип | research-article |
| DOI | 10.1039/DC9837500131 |
| Print ISSN | 0301-7249 |
| Журнал | Faraday Discussions of the Chemical Society |
| Том | 75 |
| Первая страница | 131 |
| Последняя страница | 140 |
