| Автор | Gunasekaran, Somasundaram |
| Автор | Venkatasubramanian, Nagaswami |
| Дата выпуска | 1983 |
| dc.description | Bromamine T (BAT) oxidises diphenylmethanol and substituted diphenylmethanols smoothly and quantitatively to the respective benzophenones in aquoeus acetic acid. Mineral acids catalyse the reaction and the rate law is found to be â d[BAT]/dt=k[BAT][Alcohol][H<sup>+</sup>]. The reaction is characterised by the absence of any kinetic isotope effect and a break in the Hammett plot with Ï values of â 4.2 and â 0.4 for the two limbs. Three alternative mechanistic pathways have been proposed involving (i) diphenylmethyl cation, (ii) a â phenonium ionâ type intermediate from the decomposition of the alkyl hypobromite ester, or (iii)ipso substitution at the benzene ring followed by dehydrobromination and aromatization. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Oxidation of diphenylmethanol by bromamine T. A kinetic and mechanistic study |
| Тип | research-article |
| DOI | 10.1039/P29830000949 |
| Electronic ISSN | 1364-5471 |
| Print ISSN | 0300-9580 |
| Журнал | Journal of the Chemical Society, Perkin Transactions 2 |
| Первая страница | 949 |
| Последняя страница | 953 |
| Выпуск | 7 |
