Hydride induced conversion of an ent-beyer-15-ene 12-p-tosylhydrazone into the novel ent-16S-atis-13-ene system
Pegel, Karl H.; Piacenza, Lorenzo P. L.; Phillips, Lawrence; Waight, Eric S.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1973
Аннотация:
The hydride induced shift of an ent-beyer-15-ene12-p-tosylhydrazone, a bicyclo[3,2,1]octene system, to the hitherto undescribed ent-16S-antis-13-ene, a bicyclo-[2,2,2]octene system, is discussed; the extreme unreactivity of the double bond in the product is reported.
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