Diastereoselective formation of a dipalladium(i) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged PdI–PdI bondElectronic supplementary information (ESI) available: full synthetic methods and characterisation data for compound 1 and the 2a–2f salts. See http://www.rsc.org/suppdata/cc/b3/b300177f/
Jo Ling Foo, S.; D. Jones, Nathan; O. Patrick, Brian; R. James, Brian; Jo Ling Foo S.; Department of Chemistry, University of British Columbia; D. Jones Nathan; Department of Chemistry, University of British Columbia; O. Patrick Brian; Department of Chemistry, University of British Columbia; R. James Brian; Department of Chemistry, University of British Columbia
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
The ligand CH2(P(o-C6H4NMe2)2)2 (dmapm) gives access to the first example of a dipalladium(i) complex supported by a tetradentate ligand, Pd2Cl2(μ-N,P,P,N-dmapm), which, unlike the well-known Pd2X2(μ-dppm)2 complexes (X = halide, dppm = bis(diphenylphosphino)methane), reacts with thiols to give addition of RSâ H across a phosphine-bridged Pdâ Pd bond.
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