The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complexElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b301251d/
Pechmann, Thomas; Brandt, Carsten D.; Werner, Helmut; Pechmann Thomas; Institut für Anorganische Chemie der Universität Würzburg; Brandt Carsten D.; Institut für Anorganische Chemie der Universität Würzburg; Werner Helmut; Institut für Anorganische Chemie der Universität Würzburg
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
The dinuclear complex [Rh2I2(μ-CPh2)2(μ-PMe3)] was prepared from the Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to contain the PMe3 ligand in a truly symmetrical bridging position; a new synthetic route to migrate more bulky phosphines such as PPh3 and P<sup>i</sup>Pr3 from a terminal into a bridging site is also described.
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