Charge assisted chiral hybrid H-bonded molecular networksElectronic supplementary information (ESI) available: synthetic details. See http://www.rsc.org/suppdata/cc/b3/b301467n/
Ferlay, Sylvie; Holakovsky, Roman; Hosseini, Mir Wais; Planeix, Jean-Marc; Kyritsakas, Nathalie; Ferlay Sylvie; Laboratoire de Chimie de Coordination Organique, Service Commun des Rayons X, Université Louis Pasteur; Holakovsky Roman; Laboratoire de Chimie de Coordination Organique, Service Commun des Rayons X, Université Louis Pasteur; Hosseini Mir Wais; Laboratoire de Chimie de Coordination Organique, Service Commun des Rayons X, Université Louis Pasteur; Planeix Jean-Marc; Laboratoire de Chimie de Coordination Organique, Service Commun des Rayons X, Université Louis Pasteur; Kyritsakas Nathalie; Service Commun des Rayons X, Université Louis Pasteur
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
The co-crystallisation of [Fe(CN)5NO]<sup>2â </sup> and cyclic achiral 1<sup>2+</sup> and chiral 2<sup>2+</sup> or 3<sup>2+</sup> bisamidinium tectons leads in the crystalline phase to the formation of 1-D H-bonded achiral and chiral molecular networks respectively. In all cases, the network is formed by mutual bridging of the anionic and cationic units through a chelate mode of H-bonding.
282.6Кб