Metallo-phosphorylation of alkynes: reaction of alkynes with Cp2Zr(1-butene)(PR3) and chlorophosphateElectronic supplementary information (ESI) available: experimental procedures and NMR data. See http://www.rsc.org/suppdata/cc/b3/b308595c/
Lai, Chunbo; Xi, Chanjuan; Chen, Chao; Ma, Mingming; Hong, Xiaoyin; Lai Chunbo; Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University; Xi Chanjuan; Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University; Chen Chao; Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University; Ma Mingming; Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University; Hong Xiaoyin; Key Laboratory for Bioorganic Phosphorus Chemistry of Ministry of Education, Department of Chemistry, Tsinghua University
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
Reaction of alkynes with Cp2ZrBu2 and chlorophosphate in the presence PR3 to form zircono-alkenylphosphonates, which can be converted into various β-functionalized alkenylphosphonates.
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