Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing groupElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b2/b210857g/
Matsumoto, Masakatsu; Mizuno, Toshiyuki; Watanabe, Nobuko; Matsumoto Masakatsu; Department of Materials Science, Kanagawa University; Mizuno Toshiyuki; Department of Materials Science, Kanagawa University; Watanabe Nobuko; Department of Materials Science, Kanagawa University
Журнал:
Chemical Communications
Дата:
2003
Аннотация:
A new type of dioxetane bearing a 3-(cyanomethyl)phenyl (1a), 3-(methoxycarbonylmethyl)phenyl (1b), 3-(benzoylmethyl)phenyl (1c), or 3-[cyano(methoxycarbonyl)methyl]phenyl group (1d) decomposed through an intermediary dioxetane bearing a benzylic carbanion to afford crimson to yellow light on treatment with TBAF in DMSO.
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