The photophysics of nitrocarbazoles studied by using spectroscopic, photoacoustic and luminescence techniquesDedicated to Professor Silvia Braslavsky, to mark her great contribution to photochemistry and photobiology particularly in the field of photothermal methods.
Mesaros, Mariana; Bonesi, Sergio M.; Ponce, Maria A.; Erra-Balsells, Rosa; Bilmes, Gabriel M.; Mesaros Mariana; Centro de Investigaciones Opticas (CONICET-CIC); Bonesi Sergio M.; CIHIDECAR-CONICET, Departamento de QuÃmica Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires; Ponce Maria A.; CIHIDECAR-CONICET, Departamento de QuÃmica Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires; Erra-Balsells Rosa; CIHIDECAR-CONICET, Departamento de QuÃmica Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires; Bilmes Gabriel M.; Centro de Investigaciones Opticas (CONICET-CIC) y Universidad Nacional de La Plata
Журнал:
Photochemical & Photobiological Sciences
Дата:
2003
Аннотация:
The photophysical behaviour of 1-nitrocarbazol and 3-nitrocarbazol in different organic solvents has been studied by using spectroscopic, luminescence and photoacoustic techniques. Absorption spectra and triplet state transient spectra were recorded and formation quantum yields and lifetimes determined. Phosphorescence emission at 77 K and laser induced luminescence in acetonitrile solution at 298 K for the nitrocarbazoles were studied. Results are discussed in terms of the optimized structure of 1-nitrocarbazole and 3-nitrocarbazole and compared with that of carbazole. The nitro group attached to the carbazole moiety induces important changes in the photophysical behavior of those compounds.
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