Novel anionic cages from ‘alkylmanganese chloride’ and ‘alkylcobalt chloride’ solutions. Crystal and molecular structure of [Li(thf)4][{(Me3Si)3C}3Mn3Cl4(thf)](thf = tetrahydrofuran)
Eaborn, Colin; Hitchcock, Peter B.; Smith, J. David; Sullivan, Alice C.
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1985
Аннотация:
The reaction between tris(trimethylsilyl)methyl-lithium and manganese(II) or cobalt(II) chloride yields lithium salts with chloride-bridged polynuclear anions; the manganese compound [Li(thf)4][{(Me3Si)3C}3Mn3Cl4(thf)](thf = tetrahydrofuran) has been characterised by an X-ray study.
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