| Автор | Hambley, Trevor W. |
| Дата выпуска | 1986 |
| dc.description | The crystal structure of [Ni(tmtactd)][CF3SO3]2·Me2CO·H2O has been determined by X-ray diffraction methods. The crystals are triclinic, space group P1.macr;, with a= 9.142(1), b= 13.674(2), c= 13.694(2)à , α= 61.07(1), β= 83.14(1), γ= 84.54(1)°, and Z= 2. The complex cation is four-co-ordinate with a tetrahedral distortion from square-planar geometry. Strain-energy minimization analysis by the molecular mechanics method shows that for four-co-ordinate complexes the R,S,R,S isomer is preferred, while for six-co-ordinate complexes the R,S,R,S isomer is preferred. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | The crystal structure of R,S,R,S-(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis(trifluoromethanesulphonate)–acetone hydrate, [Ni(tmtactd)][CF3SO3]2·Me2CO·H2O, and a strain-energy minimization analysis of four-, five-, and six-co-ordinate nickel(II)–tmtactd solvento complexes |
| Тип | research-article |
| DOI | 10.1039/DT9860000565 |
| Electronic ISSN | 1364-5447 |
| Print ISSN | 1472-7773 |
| Журнал | Journal of the Chemical Society, Dalton Transactions |
| Первая страница | 565 |
| Последняя страница | 569 |
| Выпуск | 3 |
