| Автор | Bell (née Tate), Vivien L. |
| Автор | Giddings, Peter J. |
| Автор | Holmes, Andrew B. |
| Автор | Mock, Graham A. |
| Автор | Raphael, Ralph A. |
| Дата выпуска | 1986 |
| dc.description | Novel syntheses of the alkenediones (12; R = Me, or CH2Ph) and the corresponding epoxides (13) are described. Attempts to cyclise these compounds to the spirocyclic dienone (4) were unsuccessful. Model studies on the phenolic keto cyano toluene-p-sulphonate (24) showed that the cyclopropane (25) was formed preferentially. A variety of related model compounds (29), (31), (32), and (37) were prepared and studied, but none could be cyclised to spirocyclic dienones. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Studies on the synthesis of aphidicolin. Preparation of aromatic precursors for spirocyclic dienone formation |
| Тип | research-article |
| DOI | 10.1039/P19860001515 |
| Electronic ISSN | 1364-5463 |
| Print ISSN | 0300-922X |
| Журнал | Journal of the Chemical Society, Perkin Transactions 1 |
| Первая страница | 1515 |
| Последняя страница | 1522 |
