Автор | Chen, Jiabi |
Автор | Lei, Guixin |
Автор | Jin, Zhongsheng |
Автор | Hu, Linghai |
Автор | Wei, Gecheng |
Дата выпуска | 1988 |
dc.description | Reaction of limonene(tricarbonyl)iron (1) with aryl-lithium reagents gave intermediate acylmetallates, from which, by subsequent alkylation with Et3OBF4 in aqueous solution at 0 °C, the novel complexes (η<sup>4</sup>-C10H16){C(OEt)C6H4Me-o}Fe(CO)2(4) and {(η<sup>3</sup>-C10H16)C(OEt)Ar}Fe(CO)2(2), Ar = Ph; (3), Ar =p-MeC6H4; (5); Ar =p-MeOC6H4; and (6), Ar =p-CF3C6H4 were obtained, the structures of (3) and (4) having been determined by X-ray crystallography. |
Формат | application.pdf |
Издатель | Royal Society of Chemistry |
Название | Novel reaction of limonene(tricarbonyl)iron: synthesis and crystal structure of (η4-C10H16){C(OEt)C6H4Me-o}Fe(CO)2and {(η4-C10H16)C(OEt)Ar}Fe(CO)2 |
Тип | research-article |
DOI | 10.1039/C39880000731 |
Print ISSN | 0022-4936 |
Журнал | Journal of the Chemical Society, Chemical Communications |
Первая страница | 731 |
Последняя страница | 732 |
Выпуск | 11 |