| Автор | Al-Juaid, Salih S. |
| Автор | Buttrus, Nabeel H. |
| Автор | Eaborn, Colin |
| Автор | Hitchcock, Peter B. |
| Автор | Smith, J. David |
| Автор | Tavakkoli, Kayumars |
| Дата выпуска | 1988 |
| dc.description | Tris(trimethylsilyl)methyl-lithium reacts with cadmium(II) chloride in tetrahydrofuran (thf) to give the lithium salt [Li(thf)4][Li(thf)2(µ-Cl)4{CdC(SiMe3)3}2].thf, which has a chloride-bridged anion and on heating gives tetrameric chloro[tris(trimethylsilyl)methyl]cadmium; bromo[tris(dimethylphenylsilyl)methyl]cadmium is dimeric in the solid, and, on recrystallisation from wet thf forms the hydrate [{Cd[C(SiMe2Ph)3]Br(H2O)}2].thf. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | The preparation and crystal structures of the sterically hindered lithium alkylchloroacadmate [Li(thf)4][Li(thf)2(µ-Cl)4{CdC(SiMe3)3}2].thf (thf = tetrahydrofuran), the alkylcadmium halides [{Cd[C(SiMe3)3]Cl}4] and [{Cd[C(SiMe2Ph)3]Br}2], and the hydrate [{Cd[C(SiMe2Ph)3]Br(H2O)}]2.(thf) |
| Тип | research-article |
| DOI | 10.1039/C39880001389 |
| Print ISSN | 0022-4936 |
| Журнал | Journal of the Chemical Society, Chemical Communications |
| Первая страница | 1389 |
| Последняя страница | 1391 |
| Выпуск | 20 |
