Reaction of [FeCo(CO)7(µ-CHCRH)](R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(µ-CO)-(PMe2Ph)2(µ-CHCH2)], an electronically unbalanced iron–cobalt complex
Moldes, Isabel; Ros, Josep; Yañez, Ramón; Mathieu, René; Solans, Xavier; Font-Bardí, Mercé
Журнал:
Journal of the Chemical Society, Dalton Transactions
Дата:
1988
Аннотация:
The reaction of [FeCo(CO)7(µ-CH.dbd6;CRH)](R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(µ-CH.dbd6;CPhH)] and [FeCo(CO)5(PMe2Ph)2(µ-CH.dbd6;CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(µ-CO)(PMe2Ph)2(µ-CH.dbd6;CH2)] has been solved by X-ray diffraction methods.
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