| Автор | Pócsi, István |
| Автор | Fábián, István |
| Дата выпуска | 1988 |
| dc.description | The hydrolytic processes of Ti<sup>3+</sup> and the equilibria of the Ti<sup>3+</sup>â glycine (HL) and â malonic acid (H2Lâ ²) systems were studied by pH-metry in aqueous solution (25 °C, I= 1.0 mol dm<sup>â 3</sup> KCl). It was demonstrated that more than one equilibrium model are suitable to interpret the hydrolytic reactions. In the Ti<sup>3+</sup>â glycine system the formation of complexes [TiHL]<sup>3+</sup> and [TiL]<sup>2+</sup> were identified; their stability constants are logβTiHL= 11.44 and logβTiL= 9.30. For the malonato complexes the following stepwise stability constants were determined: logK 1= 6.83, logK 2= 4.99, and logK 3= 2.84. Some aspects of the equilibrium of Ti<sup>3+</sup> are discussed. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Complex equilibria in aqueous solutions of Ti3+–glycine and –malonic acid |
| Тип | research-article |
| DOI | 10.1039/DT9880002231 |
| Electronic ISSN | 1364-5447 |
| Print ISSN | 1472-7773 |
| Журнал | Journal of the Chemical Society, Dalton Transactions |
| Первая страница | 2231 |
| Последняя страница | 2233 |
| Выпуск | 8 |
