| Автор | Mazhar-ul-Haque, Mazhar-ul-Haque |
| Автор | Freestone, Ali |
| Дата выпуска | 1977 |
| dc.description | The title compound (7) was isolated as a minor product of successive tosylation, acetylation and iodide displacement of methyl α-D-mannopyranoside (1). Crystals of the title compound are orthorhombic, space group P212121, a= 9.293(2), b= 14.220(6). c= 16.969(6)à Z= 4. The structure was solved from diffractometer data by heavy-atom techniques, and refined by block-diagonal least-squares methods to R 0.052 for 1 802 independent reflections. The results supply the constitution and absolute configuration (8). The conformation of the pyranoside ring is <sup>4</sup> C 1(.tbd6;C1) in the solid state and <sup>1</sup>H n.m.r. studies showed this to be the predominant conformation in solution also. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Crystal structure and absolute configuration of methyl 3,4-di-O-acetyl-6-deoxy-6-iodo-2-O-p-tolylsulphonyl-α-D-mannopyranoside |
| Тип | research-article |
| DOI | 10.1039/P29770001509 |
| Electronic ISSN | 1364-5471 |
| Print ISSN | 0300-9580 |
| Журнал | Journal of the Chemical Society, Perkin Transactions 2 |
| Первая страница | 1509 |
| Последняя страница | 1513 |
| Выпуск | 12 |
