Gas-phase Raman spectra of some dihalides of zinc and mercury, of ‘GaCl2’ and of GaCl2Br and GaBr2Cl
Beattie, I. R.; Horder, J. R.
Журнал:
Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Дата:
1970
Аннотация:
The Raman spectra of HgX2(X = Cl, Br, or l), ZnX2, and HgXY (X,Y= Cl, Br, or l) are reported for the gaseous monomeric species. In no case was a deformation mode identified, although formally this mode is active for linear HgXY. When the compound â GaCl2â was examined in the gas phase only bands due to GaCl and GaCl3 were identified. GaBr2Cl and GaCl2Br were identified in high-temperature gas-phase Raman studies of mixtures of GaCl3 and GaBr3.
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