The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis
Mishra, Abhudaya; Wernsdorfer, Wolfgang; Abboud, Khalil A.; Christou, George; Mishra Abhudaya; Department of Chemistry, University of Florida; Wernsdorfer Wolfgang; Laboratoire Louis Neel-CNRS; Abboud Khalil A.; Department of Chemistry, University of Florida; Christou George; Department of Chemistry, University of Florida
Журнал:
Chemical Communications
Дата:
2005
Аннотация:
Synthetic entry has been achieved into high oxidation state Mnâ Ca cluster chemistry with the preparation of [Mn13Ca2O10(OH)2(OMe)2(O2CPh)18(H2O)4]; the structure contains [Mn4CaO4] sub-units similar to that found in the photosynthetic water oxidizing complex.
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