| Автор | Izod, Keith |
| Автор | Young, Jonathan |
| Автор | Clegg, William |
| Автор | Harrington, Ross W. |
| Дата выпуска | 2005 |
| dc.description | The O-functionalised tertiary phosphine {(Me3Si)2CH}P(C6H4-2-CH2OMe)2 (9) is accessible via the reaction of {(Me3Si)2CH}PCl2 with two equivalents of in situ generated 2-LiC6H4CH2OMe. Phosphine 9 is readily deprotonated by Bu<sup>n</sup>Li to give the lithium phosphinomethanide [[{(Me3Si)2C}P(C6H4-2-CH2OMe)2]Li] (13), which undergoes metathesis reactions with the alkoxides MOR [M = Na, K, R = Bu<sup>t</sup>; M = Rb, R = 2-ethylhexyl] to give the heavier alkali metal phosphinomethanides [[{(Me3Si)2C}P(C6H4-2-CH2OMe)2]M]n in good yields [M = Na (14), n = 2; M = K (15), Rb (16), n = â ]. Compounds 9, [{(Me3Si)2CH}P(C6H4-2-CH2OMe)2LiBr]2 (10), and 14â 16 have been studied by X-ray crystallography; in the solid state 14 adopts a dimeric structure, whereas 15 and 16 crystallise as one-dimensional polymers. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Effect of peripheral donor substituents on the binding modes of phosphinomethanide ligands. Synthesis and crystal structures of alkali metal derivatives of an O-functionalised phosphinomethanide ligand |
| Тип | research-article |
| DOI | 10.1039/b502416a |
| Electronic ISSN | 1477-9234 |
| Print ISSN | 1477-9226 |
| Журнал | Dalton Transactions |
| Первая страница | 1658 |
| Последняя страница | 1663 |
| Аффилиация | Izod Keith; Department of Chemistry, School of Natural Sciences, Bedson Building, University of Newcastle |
| Аффилиация | Young Jonathan; Department of Chemistry, School of Natural Sciences, Bedson Building, University of Newcastle |
| Аффилиация | Clegg William; Department of Chemistry, School of Natural Sciences, Bedson Building, University of Newcastle |
| Аффилиация | Harrington Ross W.; Department of Chemistry, School of Natural Sciences, Bedson Building, University of Newcastle |
| Выпуск | 9 |
| Библиографическая ссылка | Izod, Adv. Inorg. Chem., 2000, 50, 33 |
| Библиографическая ссылка | Izod, Coord. Chem. Rev., 2002, 227, 153 |
| Библиографическая ссылка | Clegg, Chem. Commun., 1998, 1129 |
| Библиографическая ссылка | Hill, Organometallics, 2000, 19, 4531 |
| Библиографическая ссылка | Clegg, Organometallics, 1999, 18, 2939 |
| Библиографическая ссылка | Izod, Organometallics, 2001, 20, 367 |
| Библиографическая ссылка | Karsch, Organometallics, 1990, 9, 190 |
| Библиографическая ссылка | Clegg, Organometallics, 1999, 18, 3950 |
| Библиографическая ссылка | Izod, Organometallics, 2001, 20, 648 |
| Библиографическая ссылка | Izod, Organometallics, 2002, 21, 641 |
| Библиографическая ссылка | Kobayashi, Heterocycles, 1997, 45, 1593 |
| Библиографическая ссылка | Chuit, Angew. Chem., Int. Ed. Engl., 1993, 32, 1430 |
| Библиографическая ссылка | Carré, J. Organomet. Chem., 1995, 499, 147 |
| Библиографическая ссылка | Chuit, J. Organomet. Chem., 1996, 511, 171 |
| Библиографическая ссылка | Chandrasekaran, Inorg. Chem., 2002, 41, 5235 |
| Библиографическая ссылка | Clegg, Organometallics, 1998, 17, 5231 |
| Библиографическая ссылка | Izod, Organometallics, 2003, 22, 3684 |
| Библиографическая ссылка | Smith, Adv. Organomet. Chem., 1999, 43, 267 |
| Библиографическая ссылка | Eaborn, Angew. Chem., Int. Ed. Engl., 1995, 34, 687 |
| Библиографическая ссылка | Gynane, J. Chem. Soc., Dalton Trans., 1980, 2428 |
| Библиографическая ссылка | Khanapure, J. Org. Chem., 1990, 55, 1471 |
