Автор | Muszkat, Karol A. |
Автор | Weinstein, Meir |
Дата выпуска | 1976 |
dc.description | Proton nuclear polarization is observed in the photoreaction of aromatic vitro-compounds with 2,6-di-t-butyl-phenols. The polarization is due to a reversible abstraction of the phenol hydroxy-hydrogen by the excited triplet nitro-compound. The occurrence of polarization depends on the triplet energy of the vitro-compound and on the Oâ H bond dissociation energy of the phenol. Observation of polarization forms the basis for the estimation of the Oâ H bond dissociation energy of ArNO2H· radicals. |
Формат | application.pdf |
Издатель | Royal Society of Chemistry |
Название | Reversible hydrogen photoabstraction by nitroaromatic compounds. A chemically induced nuclear polarization study |
Тип | research-article |
DOI | 10.1039/P29760001072 |
Electronic ISSN | 1364-5471 |
Print ISSN | 0300-9580 |
Журнал | Journal of the Chemical Society, Perkin Transactions 2 |
Первая страница | 1072 |
Последняя страница | 1074 |
Выпуск | 9 |