| Автор | Sammes, Michael P. |
| Автор | Harlow, Richard L. |
| Дата выпуска | 1976 |
| dc.description | Two series of sulphones, containing respectively the cyanomethylsulphonyl and the benzylsulphonyl groups, have been prepared, in which a polar methylene group is allowed on steric grounds to interact intramolecularly with a nearby donor atom. The i.r. and <sup>1</sup>H n.m.r. spectra of these sulphones are compared with spectra of reference compounds in which no such interaction is possible. No conclusive evidence for intramolecular hydrogen bonds is found: possible causes for the observed spectral shifts are discussed. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Intramolecular hydrogen bonds involving polar carbon–hydrogen bonds: infrared and1H nuclear magnetic resonance spectra of some cyanomethyl and benzyl sulphones |
| Тип | research-article |
| DOI | 10.1039/P29760001130 |
| Electronic ISSN | 1364-5471 |
| Print ISSN | 0300-9580 |
| Журнал | Journal of the Chemical Society, Perkin Transactions 2 |
| Первая страница | 1130 |
| Последняя страница | 1135 |
| Выпуск | 10 |
