Polymerization of hex-1-ene by homogeneous zirconocene and hafnocene catalysts in compressed solution
Fries, Arno; Mise, Takaya; Matsumoto, Akira; Ohmori, Hiromiti; Wakatsuki, Yasuo
Журнал:
Chemical Communications
Дата:
1996
Аннотация:
Poly(hexene) with very high molecular weight is produced at 250 MPa (2500 atm) with (C5HMe4)2HfCl2â methyl aluminoxane (MAO) as catalyst; the dependence of the polymerization on the reaction pressure (0.1 MPaâ 1.5 GPa) and the substituent pattern of a zirconocene catalyst is described.
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