2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; structure and reactions with catechols and [PtCl2(PR3)2](R = Et or Bun)
Foreman, Mark R. St. J.; Slawin, Alexandra M. Z.; Woollins, J. Derek
Журнал:
Journal of the Chemical Society, Dalton Transactions
Дата:
1996
Аннотация:
Reaction of ferrocene (or 1,1â ²-dimethylferrocene) with P4S10 yielded Râ ²P(S)S2P(S)Râ ²(Râ ²= ferrocenyl)(or the analogous dimethylferrocene species). This compound reacted with catechols to form Râ ²P(S)O2C2 ring systems and with [PtCl2(PR3)2](R = Et or Bu<sup>n</sup>) to give [Râ ²PS3Pt(PR3)2]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.
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