Formation of cluster alkene complexes by nucleophilic attack on a vinyl hydride cluster: X-ray crystal structures of [(Ph3P)2N][Os3(CO)10{CF3(H)C:C(H)CF3}Br] and [Os3(CO)10{CF3(H)C:C(H)CF3}(PEt3)]
Dawoodi, Zain; Mays, Martin J.; Raithby, Paul R.; Henrick, Kim
Журнал:
Journal of the Chemical Society, Chemical Communications
Дата:
1980
Аннотация:
[Os3H(CO)10{CF3CCHCF3}] reacts with certain 2-electron donor ligands, L, to give cluster alkene complexes [Os3(CO)10{CF3(H)C:C(H)CF3}L]; the X-ray structures of two of these complexes (L = Br<sup>â </sup>, PEt3) are reported.
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