| Автор | Lappert, Michael F. |
| Автор | Raston, Colin L. |
| Дата выпуска | 1980 |
| dc.description | Reaction of [M(η-C5H5)2Cl2](M = Ti, Zr, or Hf) with o-C6H4[CH(SiMe3)Li(tmeda)]2(tmeda = Me2NCH2CH2NMe2) in OEt2 is stereospecific, generating the meso-metallocycle [[graphic omitted]H(SiMe3)-o}(η-C5H5)2], (1), in high yield; cyclic voltammetry of complexes (1) in tetrahydrofuran shows a reversible one-electron reduction (â E ½ <sup>red</sup>: Hf > Zr >> Ti) to yield relatively persistent M<sup> III </sup> anions (t ½ > 10 s) characterised by their e.s.r. spectra. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Metal complexes derived from a bidentate ligand possessing two chiral centres, o-C6H4[CH(SiMe3)–]2; stereospecific synthesis of the meso-metallocycles [M{CH(SiMe3)C6H4CH(SiMe3)-o}(η-C5H5)2] and their reversible one-electron reduction |
| Тип | research-article |
| DOI | 10.1039/C39800001284 |
| Print ISSN | 0022-4936 |
| Журнал | Journal of the Chemical Society, Chemical Communications |
| Первая страница | 1284 |
| Последняя страница | 1285 |
| Выпуск | 24 |
