Автор | Blinc, Robert |
Автор | Koźelj, Matjaź |
Автор | Rutar, Venceslav |
Автор | Zupanicić, Ivan |
Автор | Žecš, Boštjan |
Автор | Arend, Honza |
Автор | Kind, Raymond |
Автор | Chapuis, Gerhard |
Дата выпуска | 1980 |
dc.description | The hydrocarbon parts of (C10H21NH3)2CdCl4 and (C10H21NH3)2CuCl4 represent smectic lipid bi-layers exhibiting two structural phase transitions analogous to those in biomembranes. A<sup>13</sup>C nuclear magnetic resonance study showed that in the Cd compound the low-temperature transitions is connected with a disordering of the polar heads whereas the high-temperature transition corresponds to a partial melting of the alkyl chains. In the Cu compound the sequence of the two successive transitions is reversed. A Landau theory describing the two transitions in terms of order parameters used in the theory of smectic liquid crystals is presented. |
Формат | application.pdf |
Издатель | Royal Society of Chemistry |
Название | 13C nuclear magnetic resonance study of phase transitions in a lipid bilayer embedded in a crystalline matrix: (C10H21NH3)2CdCl4and (C10H21NH3)2CuCl4 |
Тип | research-article |
DOI | 10.1039/DC9806900058 |
Print ISSN | 0301-7249 |
Журнал | Faraday Discussions of the Chemical Society |
Том | 69 |
Первая страница | 58 |
Последняя страница | 65 |