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Автор Blinc, Robert
Автор Koźelj, Matjaź
Автор Rutar, Venceslav
Автор Zupanicić, Ivan
Автор Žecš, Boštjan
Автор Arend, Honza
Автор Kind, Raymond
Автор Chapuis, Gerhard
Дата выпуска 1980
dc.description The hydrocarbon parts of (C10H21NH3)2CdCl4 and (C10H21NH3)2CuCl4 represent smectic lipid bi-layers exhibiting two structural phase transitions analogous to those in biomembranes. A<sup>13</sup>C nuclear magnetic resonance study showed that in the Cd compound the low-temperature transitions is connected with a disordering of the polar heads whereas the high-temperature transition corresponds to a partial melting of the alkyl chains. In the Cu compound the sequence of the two successive transitions is reversed. A Landau theory describing the two transitions in terms of order parameters used in the theory of smectic liquid crystals is presented.
Формат application.pdf
Издатель Royal Society of Chemistry
Название 13C nuclear magnetic resonance study of phase transitions in a lipid bilayer embedded in a crystalline matrix: (C10H21NH3)2CdCl4and (C10H21NH3)2CuCl4
Тип research-article
DOI 10.1039/DC9806900058
Print ISSN 0301-7249
Журнал Faraday Discussions of the Chemical Society
Том 69
Первая страница 58
Последняя страница 65

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