| Автор | Raskó, János |
| Автор | Solymosi, Frigyes |
| Дата выпуска | 1980 |
| dc.description | The formation of an isocyanate complex in the NO + CO reaction on alumina- and silica-supported chromia was investigated by infrared spectroscopy. Isotopically-labelled gases were used to confirm that the bands at 2262 and 2242 cm<sup>â 1</sup> on Cr2O3/Al2O3 are due to surface isocyanate. The effects of the experimental conditions on the intensities of the above bands were investigated in detail. Isocyanate on Cr2O3/SiO2 yielded bands at 2315 and 2210 cm<sup>â 1</sup>. The band at 2210 cm<sup>â 1</sup> was assigned to Cr<sup>2+</sup>â NCO, while the bands at 2262 and 2242 cm<sup>â 1</sup> and that at 2315 cm<sup>â 1</sup> were attributed to the isocyanate complex residing on alumina and silica, respectively. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | Infrared spectroscopic study of isocyanate formation in the reaction of NO and CO over Cr2O3/Al2O3 and Cr2O3/SiO2 |
| Тип | research-article |
| DOI | 10.1039/F19807602383 |
| Print ISSN | 0300-9599 |
| Журнал | Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases |
| Том | 76 |
| Первая страница | 2383 |
| Последняя страница | 2395 |
