| Автор | Y. Grigorʼeva, Natalʼya |
| Автор | G. Tsiklauri, Paata |
| Автор | V. Buevich, Alexei |
| Дата выпуска | 1998 |
| dc.description | Hydride reduction of the 2(Z)- and 2(E)-isomers of methyl and tert-butyl 3-methyl-4-phenylthioheptenoates under standard conditions is accompanied by [1,3]-migration of the PhS group and in both cases (E)-3-methyl-2-phenylthiohept-3-en-1-ol 5 is produced, whose structure is confirmed by spectroscopic methods, instead of the expected (Z)-3-methyl-4-phenylthiohept-2- 3a and (E)-2-enol 3b; compounds 3a,b obtained under specially developed conditions undergo isomerisation to compound 5 during chromatography on SiO2 or on storage in the light of their solutions in CDCl3 or in C6D6. |
| Формат | application.pdf |
| Издатель | Royal Society of Chemistry |
| Название | An unusually easy [1,3]-migration of the PhS group in 3-methyl-4-phenylthiohept-2-en-1-ols |
| Тип | ART |
| Журнал | Mendeleev Communications |
| Том | 8 |
| Первая страница | 76 |
| Последняя страница | 77 |
| Выпуск | 2 |
